网状季胺基阴离子吸附剂制备及吸附性能

以丝瓜络为原料,采用醚化-接枝技术制备出季胺基阴离子交换吸附剂。采用电镜扫描、傅里叶红外光谱、比表面积孔径分布测定仪和元素分析仪等仪器对其进行分析和结构表征,并考察了温度、p H和硝酸盐初始浓度等因素对NO-3去除率的影响。实验结果表明,在20℃,p H值为3~10时,NO-3的吸附率可达90%左右;在不同温度下该吸附过程用Langmuir等温线模型和Freundich等温线模型描述均可;与伪一级动力学方程相比,伪二级动力学方程能更好地描述其吸附动力学方程。     

粤港澳大湾区NO2污染的时空特征及影响因素分析

利用Aura卫星搭载的臭氧观测仪（OMI）反演的对流层NO₂柱密度数据,分析了自2005年以来粤港澳大湾区（GBA）对流层NO₂柱密度的空间分布特征、时间变化趋势及其影响因素.研究结果表明GBA对流层NO₂柱密度从2005~2018年呈减少的趋势,每年递减约为2.8%.小波系数显示时间演化过程中存在9个月的主振荡周期,冬季浓度较高,夏季较低.人为排放和各种自然因素,导致了GBA对流层NO₂柱浓度月变化在时间和空间上存在明显差异,最小值和最大值分别出现在6和12月,多年平均值分别为3.9665×10¹⁵和12.3423×10¹⁵molec/cm².NO₂在空间分布上呈现明显的空间分异特征,冬季12月最明显.NO₂污染严重的高值区主要出现在中部地区,如广州市、佛山市和中山市,最大的对流层NO₂柱密度可达18.8306×10¹⁵molec/cm²,大约是周边地区的3 倍,且高污染区域向四周逐渐扩散,连成一片.低值区主要在北部的肇庆市和东部的惠州市,多年平均的对流层NO₂柱密度约为7.1400×10¹⁵molec/cm².对流层NO₂柱密度的增长率在不同区域的变化趋势呈现明显的差异,变化范围为-15×10¹⁵~6×10¹⁵molec/cm²,增长率百分比范围为-65%~65%.出现增长的地区主要是肇庆市北部和惠州市东部的低值区;对流层NO₂出现明显减少的区域集中在中部的高值区,减少量最大的地区为广州市、佛山市和中山市交界处.     

我国饲料粮区域产消平衡特征及政策启示

我国饲料粮消耗量大且增长迅速,已经成为我国粮食安全的首要影响因素,准确判断我国饲料粮的区域产消平衡特征对农业相关政策的制订具有重要的现实意义。论文在详细分析各省区不同畜牧产品粮食转化系数的基础上,对区域饲料粮的产消平衡状态及其原因进行了研究。结果显示：1）近年来我国饲料粮消费量快速上升,由2000年的21 730万t增长到2015年的30 549万t,15 a间增长了8 819万t。2）2015年生猪饲料粮消耗量最大,比例达到了44.4%,占据了我国饲料消耗总量的半壁江山。其次为禽蛋与禽肉消耗,消费占比分别为15.8%与12.7%;牛肉、羊肉、牛奶与水产品的饲料粮消费量比例均在5%~9%之间。3）2015年全国饲料粮总计短缺4 276万t,区域上呈现“北余南缺”的格局,东北黑龙江、吉林、内蒙古三省（区）成为我国最重要的饲料粮供应区域。从粮食转换系数与饲养结构来看,“北粮南运”现象是粮食资源的合理配置。论文提出三点政策建议：1）转变消费结构,增加牛肉与牛奶的消费量;2）推动“以粮为纲”向“粮经饲”三元种植结构转变;3）充分利用国际市场,从全球视角保护粮食安全。     

基于N，N─二甲基苯胺与NO_2~－─对氨基苯磺酸重氮盐的偶联反应示波极谱法测定NO_2~－

报道了利用Ｎ，Ｎ─二甲基苯胺为偶联试剂的Ｃｒｉｅｓｓ反应以示波极谱法测定ＮＯ_２~－的测试方法。在拟定的实验条件下，ＮＯ_２~－在４．０×１０~－３～４．８×１０~－１μｇ／ｍｌ范围内与极谱波波高呈良好的线性关系。环境水测定的相对标准偏差小于ｌ％，回收率在９７％～１０１％之间。     

库仑滴定法测定一氧化碳

本文就一氧化碳的测定条件和CO氧化过程中氧化剂的选择进行了研究。试验表明:ReAO_4-Ⅱ为氧化CO的活性催化剂,转化率可达100％(在300℃以上),本法简便,可用于空气中一氧化碳的测定和催化剂对CO活性测试。     

Observation of atmospheric nitrous acid with DOAS in Beijing, China

Measurements of nitrous acid （HONO） and nitrogen dioxide （NO2） in Beijing City have been performed by means of a developed differential optical absorption spectroscopy （DOAS） system based on photodiode array （PDA）, during the autumn of 2004. HONO and NO2 were simultaneously identified by their characteristic absorption bands in the spectral region between 337 nm and 372 nm with high sensibility and time resolution. The concentrations of HONO exhibit obviously diurnal variation with a nocturnal maximum and a daytime minimum. The highest HONO value up to 11.8 μg/m^3 was observed during the night of 2/3 September. Possible sources of the observed HONO were discussed. Good correlation to NO2 indicates that NO2 is a main source component. The measurement also shows direct emission of HONO is an imnortant source in strongly polluted urban area.     

己二胺有机废液在流化床中焚烧的实验研究

在实验室规模的热态流化床试验台上，进行了含5％己二胺有机废液的焚烧 实验研究，在700－900℃范围内，研究温度及空气过剩系数对NOx沿床高的变化规律，以及它们对NOx排放浓度的影响。实验结果表明，沿高度方向上NOx浓度 逐渐降低，并且存在NO2浓度大于NO浓度这一有趣现象，在900℃下氧量增加有利于密相区NO、NO2浓度的降低，说明在 有氧条件下NH2促进NOx的还原，在不同空气 过剩系数下和然相区出口NOx几乎为零 ，表明900℃是己二胺有机废液焚烧 的合适温度。     

Characteristics and source apportionment of PM2.5 under the dual influence of the Spring Festival and the COVID-19 pandemic in Yuncheng city

Based on the online and membrane sampling data of Yuncheng from January 1st to February 12th, 2020, the formation mechanism of haze under the dual influence of Spring Festival and COVID-19 (Corona Virus Disease) was analyzed. Atmospheric capacity, chemical composition, secondary transformation, source apportionment, backward trajectory, pollution space and enterprise distribution were studied. Low wind speed, high humidity and small atmospheric capacity inhibited the diffusion of air pollutants. Four severe pollution processes occurred during the period, and the pollution degree was the highest around the Spring Festival. In light, medium and heavy pollution periods, the proportion of SNA (SO₄²⁻, NO₃⁻ and NH₄⁺) was 59.6%, 56.0% and 54.9%, respectively, which was the largest components of PM_2.5; the [NO₃⁻]/[SO₄²⁻] ratio was 2.1, 1.5 and 1.7, respectively, indicating that coal source had a great influence; the changes of NOR (nitrogen oxidation ratio, 0.44, 0.45, 0.61) and SOR (sulphur oxidation ratio, 0.40, 0.49, 0.65) indicated the accumulation of secondary aerosols with increasing pollution. The coal combustion, motor vehicle, secondary inorganic sources and industrial sources contributed 36.8%, 26.59%, 11.84% and 8.02% to PM_2.5 masses, respectively. Backward trajectory showed that the influence from the east was greater during the Spring Festival, and the pollutants from the eastern air mass were higher, which would aggravate the pollution. Meteorological and Spring Festival had a great impact on heavy pollution weather. Although some work could not operate due to the impact of the COVID-19 epidemic, the emission of pollutants did not reduce much.     

船舶柴油机NOx后处理技术的进展

根据国内外的降低NOx排放方面最新的成果和科研动态，主要介绍了当前正在研究或者已经应用于实际的有效降低柴油机NOx排放的技术措施，并分析了各种技术方法的特点和在实际应用过程中面临的问题。     

Adsorption performance of CMK-3 and C-FDU-15 in NO removal at low temperature

CMK-3 and C-FDU-15 samples were synthesized using hard-templating and evaporationinduced self-assembly(EISA) methods,respectively.The pore structures of CMK-3 and CFDU-15 as well as commercial activated carbon were characterized by means of X-ray diffraction,field emission scanning electron microscopy,transmission electron microscopy,and N_2 adsorption–desorption.Adsorption of NO was investigated by means of thermogravimetric analysis,temperature-programmed desorption of NO + O_2,and in situ diffuse reflectance Fourier transform infrared spectroscopy.The results show that the CMK-3 and C-FDU-15 materials possessed ordered and uniform structures.The coadsorption capacity of NO and O_2 decreased in the sequence CMK-3(88.6 mg/g) C-FDU-15(71.7 mg/g) AC(25.3 mg/g).There were two main adsorption species on CMK-3 and CFDU-15:nitrite and nitrate.Nitrite is converted to nitrate easily.However,the adsorption species were more complex on AC,with nitrite being the main species.Moreover,CMK-3 and C-FDU-15 exhibit excellent regeneration efficiency compared with AC.The excellent NO adsorption performance of CMK-3 and C-FDU-15 was associated with their ordered mesoporous structures and high surface areas.The research provides more options for NO adsorption in the future.